Super bulky α-diimine ligands and their coordination complexes for use as polymerization catalysts

The TiCl4 mediated condensation of benzil with anilines followed by Li mediated cyclodehydrogenation of the resulting benzildiimines to access the superbulky a-dimine ligands Ll (N,N'-bis-(2,6-diisopropylphenyl)-phenanthrene-9, 1 O-diylidendiamine) and L2 (N-(2,6- diisopropylphenyl)-N'-(2,...

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Bibliographic Details
Main Author: Megrahi, Abdunnaser
Published: University of Manchester 2009
Subjects:
Online Access:http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.505376