Mechanism-guided studies of Brønsted acid and base organocatalysis
We have studied the mechanism of the reaction of N-Boc imines and acetylacetone in the presence and absence of chiral phosphoric acid catalysts. In order to gain mechanistic insight into the asymmetric Mannich reaction, a structurally homologous series of N-Boc imines and BINOL-derived phosphoric ac...
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Durham University
2010
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| Online Access: | http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.512959 |