Total synthesis of alkyl citrate and resorcylate natural products
The total synthesis of citrafungin A (i),1 the determination of the absolute stereochemistry2 of CJ-13,981 (ii) and CJ-13,982 (iii) and the formal total synthesis of (–)-trachyspic acid, by making lactone iv,3 were achieved from a common intermediate (v). [Diagram omitted] Dioxolanone v was prepared...
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Imperial College London
2009
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| Online Access: | http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.514565 |