Mechanistic studies on the role of cationic palladium hydride initiators in addition polymerization of exo-and endo-functionalized norbornenes
The key bicyclic carbons within the monomer structures displayed no regular or consistent trends in (^13)C NMR signal shifts, upon the methylene spacing of the –CO(_2)TMS, -OMe, -NHSO(_2)CF(_3) and –Oac functionalities. Theoretical calculations are performed on isolated molecules of endo- and exo-NB...
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Durham University
2008
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| Online Access: | http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.549872 |