Cobaltocenium functionalised {2Fe2S}-assemblies of relevance to the [FeFe]-hydrogenases
The work contained in this thesis focuses on the synthesis, electrochemistry and reactivity of {2Fe2S}-chemical models of the "H-cluster" found in [FeFe]-hydrogenase enzymes. This active subsite is comprised of a diiron organometallic subsite ligated by dithiolate, CO and CN groups, and is...
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University of East Anglia
2011
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| Online Access: | http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.551104 |