I. Group 14 metal alkoxides : synthesis and reactivity studies II. Synthesis of novel planar chiral complexes based on [2.2]paracyclophane

I. A series of group 14 β-­diketiminate alkoxides (BDI)EOR (BDI = [CH{(CH3)CN-­‐2,6-­‐iPr2C6H3}2; E = Ge, Sn, Pb; R = iPr, sBu, tBu) was synthesised and characterised. The reactivity towards aliphatic and unsaturated electrophiles was investigated. For the tin and lead systems, an unexpected trend w...

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Bibliographic Details
Main Author: Ferro, Lorenzo
Published: University of Sussex 2011
Subjects:
Online Access:https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.554618