Cobalt PCP pincer and rhodium diphosphine complexes as methanol homologation catalysts

The first two examples of cobalt phosphine PCP pincer complexes, [Co{2,6- (CH2PPh2-KPhC6H3-K[1}(COh] and [Co{2,6-(CH2PPh2-KPhC6H3-KC1}(PMe3h] have been synthesised from the precursors [CoCl(PMe3)3] and [CO(CH3) (PMe3)4]. Both pincer complexes possess pseudo-trigonal bipyramidal geometry with the coo...

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Bibliographic Details
Main Author: Kent, Mark Alexander
Published: University of Bristol 2012
Subjects:
Online Access:http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.566818