Synthesis of Ce(IV) and Ti(IV) alkoxides for use as precursors for MOCVD and ALD

A synthetic route for the general synthesis of Ce(IV) alkoxides is described utilising a reaction with eerie ammonium nitrate and tert-butoxide to create the in situ intermediate [Ce(OBut)4] by means of salt metathesis. A further alkoxy- exchange reaction with the desired alkoxide resulted in the fo...

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Bibliographic Details
Main Author: Wrench, Jacqueline Samantha
Published: University of Liverpool 2011
Subjects:
Online Access:http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.569253