Towards the total synthesis of diaporthichalasin
(2E,4E,6E,8E)-2,4,6,8-Tetramethyldeca-2,4,6,8-tetraen-1-ol 267 was synthesised via three successive sequence of reactions comprising Horner-Wadsworth-Emmons olefination, followed by DIBAL-H reduction and then oxidation with activated manganese dioxide. When coupled with mono-methyl fumarate 273, the...
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University of Manchester
2013
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| Online Access: | http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.576836 |