A structural and mechanistic understanding of copper(II)-bis(oxazoline) catalysed asymmetric aziridination : an EPR and ENDOR investigation

X- and Q-band EPR/ENDOR spectroscopy was used to study the structure of a series of heteroleptic and homoleptic copper(II)-bis(oxazoline) complexes, based on the (−)-2,2′-isopropylidenebis[(4S)-4-phenyl-2-oxazoline] (1) ligand and bearing different counterions (chloride versus triflate); labelled [C...

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Bibliographic Details
Main Author: Owen, Mari Elena
Published: Cardiff University 2013
Subjects:
546
Online Access:http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.590359