Chemoenzymatic oxidation of arenes : versatile intermediates for organic synthesis
Chapter 2 describes the chemoenzymatic synthesis of (-)epibatidine from a known cis-dihydrodiol. Crucia to the synthesis is a [3.3] sigmatropic rearrangement reaction. Two [3.3] sigmatropic rearrangements are described ; an allylazide rearrangement and an allylcyanate to isocyanate rearrangement. Th...
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Queen's University Belfast
2013
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| Online Access: | http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.602501 |