Structural characterisation of Cu(II) complexes of biological relevance : an EPR and ENDOR investigation

ENDOR spectroscopy and DFT calculations were used for the first time to thoroughly investigate the ligand hyperfine couplings for [Cu(acac)2] in frozen solution. Anisotropic hyperfine couplings to the methine protons (HAi = 1.35, -1.62, -2.12 MHz; aiso = -0.80 MHz) and smaller couplings to the fully...

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Bibliographic Details
Main Author: Sharples, Katherine Mary
Published: Cardiff University 2014
Subjects:
543
Online Access:http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.629847