Reduction and desymmetrisation of the uranyl dication in a macrocyclic framework
The transamination reaction between a Schiff base polypyrrolic macrocycle, H4Ltet/oct, where tet = tetramethyl (C38H36N8), oct = octamethyl (C42H44N8), and [UO2(THF)2{N(SiMe3)2}] results in the sole formation of mono uranyl complexes [UO2(THF)(H2Ltet)], 7, and [UO2(THF)(H2Loct)], 8. The molecular st...
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University of Edinburgh
2009
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| Online Access: | http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.633864 |