The synthesis of new perfluoroalkenyl phosphines and their use in catalysis
Exhaustive deprotonation of CF3CFH2 (HFC-134a) by two equivalents of nBuLi at low temperature gives LiCF=CF2. Immediate low temperature quench with a diethyl ether solution of RPCl(R=Ph) at low temperature affords bis substituted perfluorovinyl phosphines RP(CF=CF2)2 in excellent yield after distill...
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University of Manchester
2015
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| Online Access: | http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.654806 |