Stereocontrolled synthesis of 1,5-stereogenic centres through three-carbon homologation of boronic esters
A three carbon homologation of pinacol boronic esters has been developed. The procedure consists of a one pot Matteson homologation/alkylation followed by a palladium catalysed rearrangement from the branched to the linear allylic boronic ester. The procedure allows for the synthesis of a broad rang...
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University of Bristol
2015
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| Online Access: | http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.683456 |