Novel transition metal catalysts for intramolecular ene-reaction
We have designed a new class of MII-catalysts, namely molybdenum and tungsten (II) complexes of the type PhCH2(Et)3N+[M(CO)4C1Br2]- and M(CO)5(OTf)2 (M = Mo or W), which induce intramolecular cyclization of olefinic aldehydes to afford products with a cis-configuration at the newly formed chiral cen...
| Main Author: | |
|---|---|
| Published: |
University of Leicester
1997
|
| Subjects: | |
| Online Access: | http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.696261 |