Photochemical and thermal dediazoniations of aryl diazonium salts in non-aqueous solvents

Photodediazoniations, using a high pressure mercury lamp, of p-N,N-dimethylaminobenzenediazonium salts proceed by a heterolytic mechanism via the formation of a triplet p-N,N-dimethylaminophenyl cation. The triplet state cation has been shown to be more stable than the singlet by Gaussian 70 molecul...

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Bibliographic Details
Main Author: Hill, Howard
Published: Royal Holloway, University of London 1982
Subjects:
547
Online Access:http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.704505