Mixed valency in redox-active, all-carbon bridged bimetallic complexes of iron and molybdenum

This thesis describes the development of new procedures for the synthesis of homo- and hetero-bimetallic complexes [M-(C≡C-C≡C)-M*] linked by a butadiyndiyl (-C≡C-C≡C-) bridge (where M, M* = Mo(dppe)(η-C7H7) and Fe(dppe)Cp) and also of the diethynyl-anthracenyl bridged complex [{Mo(dppe)(-C7H7)}2(μ...

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Bibliographic Details
Main Author: Tarhuni, Sarah
Published: University of Manchester 2016
Subjects:
540
Online Access:https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.727851