Isolation, characterisation and reactivity of five-coordinate PtIV complexes

The oxidative addition to square planar dicyclometallated C^N^C PtII 16 valence electron complexes (C^N^C= 2,6-di(4-fluorophenyl)pyridine and 2-(4-fluorophenyl)-6-tertbutylpyridine) was studied with Cl2 (via PhICl2) and alkyl halides (e.g. MeI, BnBr and allylBr). The two-step nature of the process m...

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Bibliographic Details
Main Author: Shaw, Paul Anthony
Published: University of Warwick 2017
Subjects:
540
Online Access:https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.737731