Electrophilic substitution of some tetraalkytins by mercuric salts in methanol, t-butanol and methanol/t-butanol mixtures
The reaction between mercuric chloride and tetraethyl-tin, equation (1; R=Et), has been investigated using as solvent methanol, tert-butanol/methanol mixtures, and tert-butanol itself. R?4Sn + HgC12 --k2→ R3SnC1 + RHgC1 (1) On the basis of (i) positive kinetic salt effects, (ii) an increase...
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University of Surrey
1969
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| Online Access: | https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.751733 |