The development of a practical catalytic Petasus reaction of glycolaldehyde and the asymmetric allylboration of acyl cyanides
Asymmetric nucleophilic boronate reactions have been developed using organic chiral diols, specifically binaphthols, as catalysts. A highly enantioselective allylboration of acyl cyanides under solvent-free conditions was catalyzed by (S)-Br2BINOL. The reaction proceeds through single exchange of bo...
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| Language: | en_US |
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2016
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| Online Access: | https://hdl.handle.net/2144/19734 |