Redox reactions of copper complexes with fluorinated oxygen-donating ligands
Three Cu complexes varying in oxidation state from +1 to +3 were prepared from CuII starting materials and the hexafluoro-α-cumyl alkoxide ligand. These species include a targeted CuII tris-alkoxide, K[Cu(OC(C6H5)(CF3)2)3] (3); a trimeric Cu(I) complex, {K(18C6)}[K2{Cu(OC(C6H5)(CF3)2)2}3] (4); and a...
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| Language: | en_US |
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2018
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| Online Access: | https://hdl.handle.net/2144/27073 |