Reactions of organic sulphur-sulphur bonds
Rates of cleavage reactions of substituted diaryl disulphides have been measured in 60% aqueous t-butanol at 30.0°C using cyanide ion, sulphite ion and hydroxide ion as nucleophiles. Variations of substituents on the leaving group (thiophenoxide) gives results which correlate well with pK’s of th...
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| Language: | en |
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University of Canterbury. Chemistry
2011
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| Online Access: | http://hdl.handle.net/10092/6089 |