Reactive intermediates : model substrate studies
The reactions of cinnamyl chloride and crotyl chloride with various aldehydes, RCHO; R=Me, Et, iPr, CH₃(CH₂)₅, PhCH₂, Ph, p-MeOPh, p-NCPh, to form homoallylic alcohols under the control of Sn-Al, Cr(II), Zn and Mg were examined and the stereochemistry of the products determined. Stereoselectivity an...
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| Language: | en |
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University of Canterbury. Chemistry
2013
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| Online Access: | http://hdl.handle.net/10092/8316 |