I. Engaging Cationic Intermediates in Asymmetric Catalysis: Enantioselective Reactions of Carbenium Ions and N,N-Dialkyliminium Ions II. Enantioselective Catalysis of the Cope-Type Hydroamination by H-Bond Donors

I. Engaging Cationic Intermediates in Asymmetric Catalysis: Enantioselective Reactions of Carbenium Ions and N,N-Dialkyliminium Ions II. Enantioselective Catalysis of the Cope-Type Hydroamination by H-Bond Donors

The research described here explores the ability of dual H-bond donor catalysts to induce asymmetry in a variety of synthetically useful transformations that proceed via diverse reactive intermediates. In Chapters 1-3, we investigate ureas and thioureas as anion-binding catalysts for asymmetric rea...

Full description

Bibliographic Details
Main Author: Brown, Adam Ross
Other Authors: Jacobsen, Eric N.
Language:en_US
Published: Harvard University 2013
Subjects:
Chemistry
Organic chemistry
Catalysis
Hydroamination
Hydrogen-Bonding
Online Access:http://dissertations.umi.com/gsas.harvard:11009
http://nrs.harvard.edu/urn-3:HUL.InstRepos:11030585

Internet

http://dissertations.umi.com/gsas.harvard:11009
http://nrs.harvard.edu/urn-3:HUL.InstRepos:11030585

Similar Items