I. Engaging Cationic Intermediates in Asymmetric Catalysis: Enantioselective Reactions of Carbenium Ions and N,N-Dialkyliminium Ions II. Enantioselective Catalysis of the Cope-Type Hydroamination by H-Bond Donors
The research described here explores the ability of dual H-bond donor catalysts to induce asymmetry in a variety of synthetically useful transformations that proceed via diverse reactive intermediates. In Chapters 1-3, we investigate ureas and thioureas as anion-binding catalysts for asymmetric rea...
Main Author: | Brown, Adam Ross |
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Other Authors: | Jacobsen, Eric N. |
Language: | en_US |
Published: |
Harvard University
2013
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Subjects: | |
Online Access: | http://dissertations.umi.com/gsas.harvard:11009 http://nrs.harvard.edu/urn-3:HUL.InstRepos:11030585 |
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