Rhenium(V)-Imido complexes with potentially multidentate ligands containing the amino group

The complex trans-[Re(dab)Cl3(PPh3)2] (H2dab=1,2-diaminobenzene) was prepared from the reaction of trans-[ReOCl3(PPh3)2] with H2dab in ethanol. The ligand dab is coordinated to the rhenium(V) centre through a dianionic imido nitrogen only, in a distorted octahedral coordination geometry around the m...

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Bibliographic Details
Main Author: Booysen, Irvin Noel
Format: Others
Language:English
Published: Nelson Mandela Metropolitan University 2007
Subjects:
Online Access:http://hdl.handle.net/10948/479