Alkylated PTA platforms for mono- and polynuclear pre-catalysts for the aqueous biphasic hydroformylation of 1-octene
A series of mono-, di- and trimeric alkylated PTA ligands were synthesised. These ligands were reacted with the dimeric rhodium precursor, [RhCl(COD)]2, to produce the corresponding mono-, di- and trinuclear Rh(I)-PTA complexes. These complexes were then reacted with carbon monoxide to substitute th...
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Format: | Dissertation |
Language: | English |
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University of Cape Town
2019
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Online Access: | http://hdl.handle.net/11427/29206 |