Aluminium triflate-mediated reactions of glycals: towards chiral multicyclic products
Ph.D. (Chemistry) === The bridged chiral benzopyrans were strategically ring opened via acetolysis to yield either galactose based chromenes or chromans, depending on the reaction conditions. A proposal relating to the mechanism of this selective ring opening acetolysis is discussed. The benzopyrans...
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2015
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Online Access: | http://hdl.handle.net/10210/13698 |