Modification of rhenium carbonyls with thienyl nucleophiles
In the reaction between [Re(CO)5Br] and 2–lithiumthienyl, X–ligand substitution was expected. Li+{C4H3S}¯did not substitute Br¯, but an intermediate negatively charged complex was obtained (non–mobile on silica gel) and it was found that the thienyl had bonded to a carbonyl ligand, producing a dirhe...
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2013
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| Online Access: | http://hdl.handle.net/2263/28475 Olivier, AJ 2009, Modification of Rhenium carbonyls with thienyl nucleophiles , PhD thesis, University of Pretoria, Pretoria, viewed yymmdd < http://hdl.handle.net/2263/28475 > http://upetd.up.ac.za/thesis/available/etd-10062010-182746/ |