Accurate ionic bond energy measurements with TCID mass spectrometry and imaging PEPICO spectroscopy
Two projects are presented here. In the first, metal-cyclopentadienyl bond dissociation energies (BDEs) were measured for seven metallocene ions (Cp2M+, Cp = η5-cyclopentadienyl = c-C5H5, M = Ti, V, Cr, Mn, Fe, Co, Ni) using threshold collision-induced dissociation (TCID) performed in a guided ion b...
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| Format: | Others |
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Scholarly Commons
2012
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| Online Access: | https://scholarlycommons.pacific.edu/uop_etds/809 https://scholarlycommons.pacific.edu/cgi/viewcontent.cgi?article=1808&context=uop_etds |