C-glycoside syntheses: Part I. Dendritic syntheses of hexose and aminohexose C-pyranosides from 2,6-anhydro-5,7-O-benzylidene-1-deoxy-1-nitro-D-guloheptitol (82). Part II. Henry condensation of nitroethane and nitropropane with 4,6-O-benzylidene-D-glucopyranose (81)
The di-O-acetyl derivative of 4,6-O-benzylidene-1-deoxy-1-nitromethyl-β-D-glucopyranose was reduced by a mixture of elemental iron and nickel in aqueous tetrahydrofuran under CO2, with concurrent O → N acetyl migration to 1-acetamido-4-O-acetyl-2,6-anhydro-5,7-O-benzylidene-1-deoxy-D-glycero-D-guloh...
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| Format: | Others |
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Scholarly Commons
1993
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| Online Access: | https://scholarlycommons.pacific.edu/uop_etds/2936 https://scholarlycommons.pacific.edu/cgi/viewcontent.cgi?article=3935&context=uop_etds |