The experimental and theoretical determination of combinatorial kinetic isotope effects for mechanistic analysis
Unfortunately, chemists can never experimentally unravel a full reaction pathway. Even our ability to define key aspects of mechanisms, such as short-lived intermediates and the even more ephemeral transition states, is quite limited, requiring subtle experiments and subtle interpretations. Arguably...
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Format: | Others |
Language: | en_US |
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2010
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Online Access: | http://hdl.handle.net/1969.1/ETD-TAMU-1253 http://hdl.handle.net/1969.1/ETD-TAMU-1253 |