Tris(guanidinato)complexes of iridium and rhodium in the oxidation states +III and +IV: synthesis, characterization, and reactivity
Mononuclear [Ir{ArNC(NR2)NAr}(C8H14)2] complexes (where R = Me or Et; Ar = Ph or 4-MeC6H4; and C8H14 = cis-cyclooctene) were synthesized from the neutral N,N-dialkyl-N′,N′′-diarylguanidines via deprotonation and transmetalation. As confirmed by single-crystal structure determination, the guanidinato...
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| Format: | Others |
| Language: | English |
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University of Iowa
2011
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| Online Access: | https://ir.uiowa.edu/etd/2736 https://ir.uiowa.edu/cgi/viewcontent.cgi?article=2716&context=etd |