Synthetic, Mechanistic, and Structural Studies of Polynuclear Metal Clusters and Hydrazido-Substituted Tantalum(V) Compounds

A combined experimental and computational study on the reversible ortho-metalation exhibited by the triosmium cluster Os3(CO)10(dppm) (dppm = 1,1-bis(diphenylphosphino)methane is reported. The conversion of nonacarbonyl cluster HOs3(CO)9[-PhP(C6H4)CH2PPh2] to Os3(CO)10(dppm) is independe...

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Bibliographic Details
Main Author: Huang, Shih-huang
Other Authors: Richmond, Michael G.
Format: Others
Language:English
Published: University of North Texas 2010
Subjects:
Online Access:https://digital.library.unt.edu/ark:/67531/metadc33166/