Synthesis of Polycyclic "Cage" Molecules

The synthesis of a novel, cage spiro-oxetane was carried out. Pentacyclo[5.4.0.0^2,6.0^3,10.0^5,9]undecane-8- one (PCUD-8-one) undergoes one-carbon homologation to a mixture of endo- and exo- PCUD-carboxaldehydes which then are converted into 8,8-bis(hydroxymethyl)PCUD. The monotosylate obtained via...

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Bibliographic Details
Main Author: Ren, Chien-Tai
Other Authors: Marchand, Alan P.
Format: Others
Language:English
Published: University of North Texas 1989
Subjects:
Online Access:https://digital.library.unt.edu/ark:/67531/metadc500575/