Synthesis, Structure, and Solution Dynamics of Co₄(CO)₈(dmpe)(mu₄-PPh)₂
Reaction of the tetracobalt cluster Co4(CO)10(t 4-PPh)2 with 1,2-bis(dimethylphosphino)ethane (dmpe) affords the bis-substituted cluster Co4(CO)8(dmpe)(t 4-PPh)2. The bidentate dmpe ligand is shown to bind to the cluster in a chelating fashion by IR, NMR, and X-ray diffractions analyses. The flux...
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| Format: | Others |
| Language: | English |
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University of North Texas
1990
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| Online Access: | https://digital.library.unt.edu/ark:/67531/metadc501095/ |