Influence of solvent viscosity, polarity and polarizability on the chemiluminescence parameters of inter and intramolecular electron transfer initiated chemiexcitation systems

Influence of solvent viscosity, polarity and polarizability on the chemiluminescence parameters of inter and intramolecular electron transfer initiated chemiexcitation systems

The cyclic peroxides: diphenoyl peroxide (1), spiro-adamantyl-1,2-dioxetanone (2) and 4-(3-tert-butyldimethylsilyloxyphenyl)-4-methoxyspiro[1.2-dioxetane-3.2\'-adamantane] (3) synthesized, purified and characterized, also their kinetic and chemiluminescence (CL) properties were determined. The...

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Bibliographic Details
Main Author: Khalid, Muhammad
Other Authors: Baader, Josef Wilhelm
Format: Others
Language:en
Published: Biblioteca Digitais de Teses e Dissertações da USP 2015
Subjects:
Chemiluminescence
Collisional model
Cyclic peroxides
Free volume model
Modelo collisional
Modelo de volume livre
Parâmetros de solvente
Peróxidos cíclicos
Polaridade
Polarity
Polarizabilidade
Polarizability
Quantum yields
Quimiluminescência
Rendimento quântico
Solvent
Solvent parameters
Solvente
Viscosidade
Viscosity
Online Access:http://www.teses.usp.br/teses/disponiveis/46/46136/tde-29092015-114251/

Internet

http://www.teses.usp.br/teses/disponiveis/46/46136/tde-29092015-114251/

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