Development of real-time mechanistic tools for the elucidation of catalytic reaction mechanisms

Development of real-time mechanistic tools for the elucidation of catalytic reaction mechanisms

The mechanism of a conjugate addition of an alcohol to an alkynic acid ester using a phosphine catalyst was investigated using pressurized sample infusion electrospray ionization mass spectrometry (PSI-ESI-MS) and proton and phosphorus nuclear magnetic resonance (NMR) experiments. Since ESI-MS only...

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Bibliographic Details
Main Author: Stoddard, Rhonda Louise
Other Authors: McIndoe, J. Scott
Language:English
en
Published: 2014
Subjects:
ESI-MS
phosphine catalysis
ring opening metathesis polymerization
conjugate addition
cross metathesis
NMR
Piers' catalyst
Online Access:http://hdl.handle.net/1828/5560

Internet

http://hdl.handle.net/1828/5560

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