Generation Of Electron Deficient Carbodiimides And Their Application In The Guanidine Forming, Zwitterionic 1,3-Diaza-Claisen Rearrangement
The 1,3-diaza Claisen rearrangement was initially discovered by the Madalengoitia group in the early 2000s. Tertiary, allylic, amines nucleophilically add to the carbon of a heterocumulene (isocyanate, isothiocyanate, or carbodiimide) to generate a zwitterion which then undergoes [3,3]-sigmatropic r...
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| Format: | Others |
| Language: | en |
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ScholarWorks @ UVM
2017
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| Online Access: | http://scholarworks.uvm.edu/graddis/674 http://scholarworks.uvm.edu/cgi/viewcontent.cgi?article=1673&context=graddis |