Kinetics of the Gas-Phase Reaction of Hydroxyl Radicals with Dimethyl Methylphosphonate (DMMP) over an Extended Temperature Range (273–837 K)

Kinetics of the Gas-Phase Reaction of Hydroxyl Radicals with Dimethyl Methylphosphonate (DMMP) over an Extended Temperature Range (273–837 K)

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The kinetics of the reaction of hydroxyl radical (OH) with dimethyl methylphosphonate (DMMP, (CH3O)2CH3PO) (reaction 1) OH + DMMP → products (1) was studied at the bath gas (He) pressure of 1 bar over the 295–837 K temperature range. Hydroxyl radicals were produced in the fast reaction of electronic...

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Bibliographic Details
Main Authors: Barkova, D.A (Author), Chesnokov, E.N (Author), Gerasimov, I.E (Author), Koshlyakov, P.V (Author), Krasnoperov, L.N (Author), Zhang, X. (Author)
Format: Article
Language:English
Published: MDPI 2022
Subjects:
dimethyl methylphosphonate
DMMP
hydroxyl
kinetics
laser photolysis
pressure dependence
radical
transient absorption
V-shaped temperature dependence
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