Synthesis and Reactivity of Manganese Complexes Bearing Anionic PNP- and PCP-Type Pincer Ligands toward Nitrogen Fixation

A series of manganese complexes bearing an anionic pyrrole-based PNP-type pincer ligand and an anionic benzene-based PCP-type pincer ligand is synthesized and characterized. The reactivity of these complexes toward ammonia formation and silylamine formation from dinitrogen under mild conditions is e...

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Bibliographic Details
Main Authors: Kato, T. (Author), Kuriyama, S. (Author), Nishibayashi, Y. (Author), Wei, S. (Author)
Format: Article
Language:English
Published: NLM (Medline) 2022
Subjects:
ion
Online Access:View Fulltext in Publisher