Role of the support and chloride during the purification of 1-pentene in alkyne/alkene streams over Pd catalysts

Role of the support and chloride during the purification of 1-pentene in alkyne/alkene streams over Pd catalysts

BACKGROUND: Pd nanoparticles over different supports were evaluated during the alkyne selective hydrogenation of medium chain (C7 and C5) and the 1-pentene purification at mild operational conditions (150 kPa and 303 K). The role of support and chloride was investigated; γ-Al2O3, γ-Al2O3 modified wi...

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Bibliographic Details
Main Authors: Betti, C. (Author), Coloma-Pascual, F. (Author), Cordoba, M. (Author), García, L. (Author), Lederhos, C.R (Author), Martínez Bovier, L. (Author), Quiroga, M.E (Author), Ramírez, A. (Author)
Format: Article
Language:English
Published: John Wiley and Sons Ltd 2021
Subjects:
acidity
Activated alumina
activated carbon
adsorption
alkene
alkene purification
alkyne
Aluminum oxide
Article
Calcite
Calcium carbonate
Carbonate minerals
catalyst
Catalyst selectivity
Catalyst supports
Catalytic behavior
Chemical industry
chloride
Chlorine compounds
Commercial catalyst
controlled study
dispersion
Dissociative adsorption
Electronic properties
Gas adsorption
High selectivity
Hydrocarbons
hydrogen
isomerization
Isomerization
Isomerization reaction
Magnesia
magnesium
Mild reaction conditions
Operational conditions
Oxide minerals
Palladium
Palladium compounds
palladium nanoparticle
palladium nanoparticles
particle size
purification
Purification
selective hydrogenation
Selective hydrogenation
support
surface property
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