Thermal decomposition study of perchlorate-based metal-free molecular perovskite DAP-4 mixed with ammonium perchlorate

Thermal decomposition study of perchlorate-based metal-free molecular perovskite DAP-4 mixed with ammonium perchlorate

The molecular perovskite energetic materials (H2dabco)[NH4(ClO4)3] (DAP-4, H2dabco2+= 1,4-diazabicyclo[2.2.2]octane-1,4-diium), limits its separate application in explosives duo to the severe negative oxygen balance. Therefore, it is of great significance to study the thermal decomposition performan...

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Bibliographic Details
Main Authors: Feng, X.-J (Author), Pan, W. (Author), Shang, Y. (Author), Zhang, K. (Author)
Format: Article
Language:English
Published: Elsevier Ltd 2022
Subjects:
Condensed phase
Condensed phasis
Decomposition performance
Differential scanning calorimetry
Explosives
Fourier transform infrared spectroscopy
Gaseous products
Inorganic compounds
Mass spectrometry
Metal free
Mixtures
Molecular oxygen
Negative oxygen balance
Perchlorate-based molecular perovskite
Perovskite
Reaction kinetics
Redox reactions
Temperature
TG-MS-FTIR
Thermal decomposition mechanism
Thermogravimetric analysis
Thermogravimetry-mass spectrometry
Thermolysis
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