Pu(iii) and Cm(iii) in the presence of EDTA: aqueous speciation, redox behavior, and the impact of Ca(ii)

Pu(iii) and Cm(iii) in the presence of EDTA: aqueous speciation, redox behavior, and the impact of Ca(ii)

The impact of calcium on the solubility, redox behavior, and speciation of the An(iii)-EDTA (An = Pu or Cm) system under reducing, anoxic conditions was investigated through batch solubility experiments, X-ray absorption spectroscopy (XAS), density functional theory (DFT), and time-resolved laser fl...

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Bibliographic Details
Main Authors: Altmaier, M. (Author), Dardenne, K. (Author), DiBlasi, N.A (Author), Fellhauer, D. (Author), Gaona, X. (Author), Hixon, A.E (Author), Reed, D.T (Author), Rothe, J. (Author), Schnurr, A. (Author), Tasi, A.G (Author), Trumm, M. (Author)
Format: Article
Language:English
Published: Royal Society of Chemistry 2022
Subjects:
Anoxic conditions
Aqueous speciation
Density functional theory
Density-functional-theory
EDTA complex
Fluorescence spectroscopy
OH -
Plutonium compounds
Redox behavior
Redox speciation
Sodium chloride
Sodium hydroxide
Solubility
Solubility data
Time-resolved laser fluorescence spectroscopies
X ray absorption spectroscopy
X-ray absorption spectroscopy
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