Metal-organic framework structures of fused hexagonal motifs with cuprophilic interactions of a triangular Cu(i)3(pyrazolate-benzoate) metallo-linker

Metal-organic framework structures of fused hexagonal motifs with cuprophilic interactions of a triangular Cu(i)3(pyrazolate-benzoate) metallo-linker

The reaction of the N,O-heteroditopic bifunctional ligand 4-(3,5-dimethyl-1H-pyrazol-4-yl)benzoic acid (H2mpba) with Cu(NO3)2·2.5H2O and Zn(NO3)2·4H2O or Zn(CH3COO)2·2H2O in N,N-dimethylformamide (DMF) results in concomitant formation of three bimetallic metal-organic frameworks (MOFs) with open str...

Full description

Bibliographic Details
Main Authors: Beglau, T.H.Y (Author), Boldog, I. (Author), Heinen, T. (Author), Janiak, C. (Author), Menzel, S. (Author), Spieß, A. (Author), Woschko, D. (Author), Xing, S. (Author)
Format: Article
Language:English
Published: Royal Society of Chemistry 2022
Subjects:
Atoms
Benzoic acid
Bifunctional ligand
Bimetallics
Carboxylate groups
Carboxylation
Copper compounds
Dimethylformamide
Framework structures
In-phase
Ligands
Metallacycles
Metal-Organic Frameworks
Metalorganic frameworks (MOFs)
Metals
N-N-dimethylformamide
Open structure
Organic solvents
Pyrazolate
Zinc compounds
Online Access:View Fulltext in Publisher

Internet

View Fulltext in Publisher

Similar Items