Theoretical study of a derivative of chlorophosphine with aliphatic and aromatic Grignard reagents: SN2@P or the novel SN2@Cl followed by SN2@C?
The proposed SN2 reactions of a hindered organophosphorus reactant with aliphatic and aromatic nucleophiles [Ye et al., Org. Lett., 2017, 19, 5384-5387] were studied theoretically in order to explain the observed stereochemistry of the products. Our computations (using B3LYP as the functional) indic...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Royal Society of Chemistry
2022
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| Subjects: | |
| Online Access: | View Fulltext in Publisher |