Emergence and Breaking of Duality Symmetry in Generalized Fundamental Thermodynamic Relations
Thermodynamics as limiting behaviors of statistics is generalized to arbitrary systems with probability a priori where the thermodynamic infinite-size limit is replaced by a multiple-measurement limit. A duality symmetry between Massieu's and Gibbs's entropy arises in the limit of infinite...
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| Format: | Article |
| Language: | English |
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American Physical Society
2022
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| Subjects: | |
| Online Access: | View Fulltext in Publisher |