The Tail Wags the Dog: The Far Periphery of the Coordination Environment Manipulates the Photophysical Properties of Heteroleptic Cu(I) Complexes

The Tail Wags the Dog: The Far Periphery of the Coordination Environment Manipulates the Photophysical Properties of Heteroleptic Cu(I) Complexes

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In this work we show, using the example of a series of [Cu(Xantphos)(NˆN)]+ complexes (NˆN being substituted 5-phenyl-bipyridine) with different peripheral NˆN ligands, that substituents distant from the main action zone can have a significant effect on the physicochemical properties of the system....

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Bibliographic Details
Main Authors: Grachova, E. (Author), Gurzhiy, V. (Author), Koshevoy, I. (Author), Levin, O. (Author), Luginin, M. (Author), Melnikov, A. (Author), Paderina, A. (Author), Petrovskii, S. (Author), Sizov, V. (Author), Slavova, S. (Author)
Format: Article
Language:English
Published: MDPI 2022
Subjects:
bipyridine derivative
chemistry
Coordination Complexes
coordination compound
copper
Copper
copper(I) complex
ligand
Ligands
luminescence
Luminescence
quantum chemical calculation
spectroscopy
Spectrum Analysis
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