Stereoselectivity of the Honda-Reformatsky reaction in reactions with ethyl bromodifluoroacetate with ?-oxygenated sulfinylimines
The Reformatsky reaction of ethyl bromodifluoroacetate to ?-oxygenated sulfinylimines is described. Using Honda-Reformatsky conditions, the reaction proceeds with double diastereodifferentiation, with the configuration of the sulfinyl group determining the stereochemical course of the reaction. Exce...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
2014.
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| Subjects: | |
| Online Access: | Get fulltext |